Evaluating Groundwater Quality Using Multivariate Statistical Analysis and Groundwater Quality Index

Nguyen Quoc Pham, Giao Thanh Nguyen

Abstract


Under pressure from surface water pollution and climate change, groundwater becomes a critical water source. Information on groundwater quality could contribute to effective groundwater management. This study was carried out to utilize multivariate statistical analysis and the groundwater quality index (GWQI) to evaluate groundwater quality in Ca Mau Province, Vietnam. Twenty-five groundwater samples from residential-urban areas, cemetery areas, landfill areas, and saline intrusion areas were collected for this study. Groundwater quality was evaluated using the National Technical Regulation on Groundwater Quality (QCVN 09-MT:2015/BTNMT) and GWQI. Principal component analysis (PCA) was used to identify potential polluting sources and key variables influencing groundwater quality. Cluster analysis (CA) was applied to cluster groundwater quality, and the sites were recommended for future monitoring. The results revealed that NH4+-N contaminated groundwater in the landfill area, while the saline intrusion area was polluted by TDS and NH4+-N. The groundwater quality classified as excellent, good, poor, and very poor accounted for 44, 40%, 12%, and 4%, respectively. Cluster analysis divided groundwater quality into four groups, mainly based on the presence of NH4+-N and TDS. Nine groundwater sampling locations could be removed from the current groundwater quality program but still ensuring representativeness as a result of CA. PCA proposed two main sources of variation in groundwater quality at each residential-urban area: the cemetery area, the landfilling area, and the saline intrusion area. The groundwater parameters (i.e., pH, TDS, permanganate index, NH4+-N, NO3--N, and Fe) should be continued to monitor. Domestic and industrial wastewater discharge, leachate from cemeteries and landfills, the nature of groundwater aquifers, and seawater intrusion could be potential sources of groundwater variation. The current findings provide scientific information for local environmental authorities to manage and monitor groundwater quality in the study area.

 

Doi: 10.28991/CEJ-2024-010-03-03

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Keywords


Ammonium; Ca Mau Peninsula; Groundwater Quality Index (GWQI); Multivariate Analysis.

References


Earman, S., & Dettinger, M. (2011). Potential impacts of climate change on groundwater resources - A global review. Journal of Water and Climate Change, 2(4), 213–229. doi:10.2166/wcc.2011.034.

Amanambu, A. C., Obarein, O. A., Mossa, J., Li, L., Ayeni, S. S., Balogun, O., Oyebamiji, A., & Ochege, F. U. (2020). Groundwater system and climate change: Present status and future considerations. Journal of Hydrology, 589, 125163. doi:10.1016/j.jhydrol.2020.125163.

Elemile, O. O., Ibitogbe, E. M., Folorunso, O. P., Ejiboye, P. O., & Adewumi, J. R. (2021). Principal component analysis of groundwater sources pollution in Omu-Aran Community, Nigeria. Environmental Earth Sciences, 80(20), 690–707. doi:10.1007/s12665-021-09975-y.

Barbieri, M., Barberio, M. D., Banzato, F., Billi, A., Boschetti, T., Franchini, S., Gori, F., & Petitta, M. (2023). Climate change and its effect on groundwater quality. Environmental Geochemistry and Health, 45(4), 1133–1144. doi:10.1007/s10653-021-01140-5.

Liu, Q., Wang, G., Gui, D., Liu, Y., Kotb Abd-Elmabod, S., & Wei, G. (2024). Precise ecological restoration under water diversions-groundwater-ecosystem interactions in drylands. Journal of Hydrology, 628, 130601. doi:10.1016/j.jhydrol.2023.130601.

Wada, Y., Van Beek, L. P. H., Van Kempen, C. M., Reckman, J. W. T. M., Vasak, S., & Bierkens, M. F. P. (2010). Global depletion of groundwater resources. Geophysical Research Letters, 37(20), 20402. doi:10.1029/2010GL044571.

Maharjan, A. K., Mori, K., & Toyama, T. (2020). Nitrogen removal ability and characteristics of the laboratory-scale tidal flow constructed wetlands for treating ammonium-nitrogen contaminated groundwater. Water (Switzerland), 12(5), 1326. doi:10.3390/W12051326.

Laonamsai, J., Pawana, V., Chipthamlong, P., Chomcheawchan, P., Kamdee, K., Kimmany, B., & Julphunthong, P. (2023). Groundwater Quality Variations in Multiple Aquifers: A Comprehensive Evaluation for Public Health and Agricultural Use. Geosciences (Switzerland), 13(7), 195. doi:10.3390/geosciences13070195.

Abdessamed, D., Jodar-Abellan, A., Ghoneim, S. S. M., Almaliki, A., Hussein, E. E., & Pardo, M. Á. (2023). Groundwater quality assessment for sustainable human consumption in arid areas based on GIS and water quality index in the watershed of Ain Sefra (SW of Algeria). Environmental Earth Sciences, 82(21), 510. doi:10.1007/s12665-023-11183-9.

UNESCO. (2022). Groundwater: Making the invisible visible. The United Nations Educational, Scientific and Cultural Organization (UNESCO), Paris, France. Available online: https://www.unesco.org/reports/wwdr/2022/en (accessed on February 2024).

Scanlon, B. R., Fakhreddine, S., Rateb, A., de Graaf, I., Famiglietti, J., Gleeson, T., Grafton, R. Q., Jobbagy, E., Kebede, S., Kolusu, S. R., Konikow, L. F., Long, D., Mekonnen, M., Schmied, H. M., Mukherjee, A., MacDonald, A., Reedy, R. C., Shamsudduha, M., Simmons, C. T., … Zheng, C. (2023). Global water resources and the role of groundwater in a resilient water future. Nature Reviews Earth & Environment, 4(2), 87–101. doi:10.1038/s43017-022-00378-6.

Lu, X., Fan, Y., Hu, Y., Zhang, H., Wei, Y., & Yan, Z. (2024). Spatial distribution characteristics and source analysis of shallow groundwater pollution in typical areas of Yangtze River Delta. Science of the Total Environment, 906, 167369. doi:10.1016/j.scitotenv.2023.167369.

Obeidat, M., & Awawdeh, M. (2021). Assessment of groundwater quality in the area surrounding Al-Zaatari Camp, Jordan, using cluster analysis and water quality index (WQI). Jordan Journal of Earth & Environmental Sciences, 12(3), 187-197.

Ferhati, A., Kettab, R. M., Belazreg, N. E. H., Khodja, H. D., Djerbouai, S., & Hasbaia, M. (2023). Hydrochemical analysis of groundwater quality in central Hodna Basin, Algeria: a case study. International Journal of Hydrology Science and Technology, 15(1), 22. doi:10.1504/ijhst.2023.127889.

Nguyen, T. G., & Huynh, N. T. H. (2023). Characterization of Groundwater Quality and Human Health Risk Assessment. Civil Engineering Journal (Iran), 9(3), 618–628. doi:10.28991/CEJ-2023-09-03-09.

Zohud, A., & Alam, L. (2022). A Review of Groundwater Contamination in West Bank, Palestine: Quality, Sources, Risks, and Management. Water (Switzerland), 14(21), 3417. doi:10.3390/w14213417.

Khezami, F., Gómez-Navarro, O., Barbieri, M. V., Khiari, N., Chkirbene, A., Chiron, S., Khadhar, S., & Pérez, S. (2024). Occurrence of contaminants of emerging concern and pesticides and relative risk assessment in Tunisian groundwater. Science of the Total Environment, 906, 167319. doi:10.1016/j.scitotenv.2023.167319.

Giao, N. T., Anh, P. K., & Nhien, H. T. H. (2022). Groundwater Quality Assessment Using Groundwater Quality Index and Multivariate Statistical Methods and Human Health Risk Assessment in a Coastal Region of the Vietnamese Mekong Delta. Applied Environmental Research, 44(2), 68–85. doi:10.35762/AER.2022.44.2.6.

Nguyen, A. H., Pham, N. T. T., Tat, V. H. M., Truong, H. T., Tran, H. N., Luu, L. K., Tran, B. M., & Luong, H. T. H. (2020). Application of groundwater quality index (GWQI) and GIS in groundwater quality zoing in Pleistocene aquifer in Phu My town, Ba Ria – Vung Tau province. Science & Technology Development Journal - Science of the Earth & Environment, 4(1), 149-161. doi:10.32508/stdjsee.v4i1.525.

Li, Q., Zhang, H., Guo, S., Fu, K., Liao, L., Xu, Y., & Cheng, S. (2020). Groundwater pollution source apportionment using principal component analysis in a multiple land-use area in southwestern China. Environmental Science and Pollution Research, 27(9), 9000–9011. doi:10.1007/s11356-019-06126-6.

Le, Q. T., Nguyen, K. V., & Nguyen, V. D. T. (2022). Assessment of surface water quality and some main rivers’ capacity of receiving wastewater in Ca Mau province, Vietnam. The Journal of Agriculture and Development, 21(3), 53-66. doi:10.52997/jad.7.03.2022.

Giao, N. T. (2022). Analysis of Surface Water Quality using Multivariate Statistical Approaches: A case study in Ca Mau Peninsula, Vietnam. Pollution, 8(2), 463–477. doi:10.22059/POLL.2021.329252.1165.

Be, N. V., & Tuyen, T. T. (2007). Status of exploitation, management and quality of sand dune groundwater in Tra Vinh Province. Journal of Science Can Tho University, 8, 95-104.

Giao, N. T. (2021). Chemical and microbial characteristics of surface and ground water in the areas burying swine infected with African swine fever, An Giang province, Vietnam. Journal of Energy Technology and Environment, 3(3), 9–20. doi:10.37933/nipes.e/3.3.2021.2.

DoENR (2022). Environmental Report in Ca Mau Province. Department of Environment and Natural Resources (DoENR), Ca Mau, Vietnam. Available online: https://documents1.worldbank.org/curated/ru/660481568009638284/pdf/Environmental-and-Social-Impact-Assessment-for-Ca-Mau-Province.pdf (accessed on January 2024).

Rice, W. E., Baird, R. B. & Eaton, A. D. (2017). Standard Methods of for the Examination of Water and Wastewater (23rd Ed.). American Public Health Association, Washington, United States.

QCVN 09-MT:2015/BTNMT. (2015). National technical regulation on groundwater quality. Ministry of Natural Resources and Environment (MONRE), Hanoi, Vietnam. (In Vietnamese).

Nguyen, B. T., Nguyen, T. M. T., & Bach, Q. V. (2020). Assessment of groundwater quality based on principal component analysis and pollution source-based examination: a case study in Ho Chi Minh City, Vietnam. Environmental Monitoring and Assessment, 192(6), 395. doi:10.1007/s10661-020-08331-0.

Taşan, M., Demir, Y., & Taşan, S. (2022). Groundwater quality assessment using principal component analysis and hierarchical cluster analysis in Alaçam, Turkey. Water Supply, 22(3), 3431–3447. doi:10.2166/WS.2021.390.

Piyathilake, I. D. U. H., Ranaweera, L. V., Udayakumara, E. P. N., Gunatilake, S. K., & Dissanayake, C. B. (2022). Assessing groundwater quality using the Water Quality Index (WQI) and GIS in the Uva Province, Sri Lanka. Applied Water Science, 12(4), 72–90. doi:10.1007/s13201-022-01600-y.

Talalaj, I. A., & Biedka, P. (2016). Use of the landfill water pollution index (LWPI) for groundwater quality assessment near the landfill sites. Environmental Science and Pollution Research, 23(24), 24601–24613. doi:10.1007/s11356-016-7622-0.

QCVN 01-1:2018/BYT. (2018). National technical regulation on quality of clean water used for domestic purposes. Ministry of Natural Resources and Environment (MONRE), Hanoi, Vietnam. (In Vietnamese).

Tham, T. T., Thi Hien, D., Thuy Chung, N., & Tra Mai, N. (2022). Assessment of Groundwater Quality in the Holocene Aquifer in Duy Tien District, Ha Nam Province using Groundwater Quality Index (GWQI). VNU Journal of Science: Earth and Environmental Sciences, 38(1), 95–104. doi:10.25073/2588-1094/vnuees.4781.

Singh, G., Singh, J., Wani, O. A., Egbueri, J. C., & Agbasi, J. C. (2024). Assessment of groundwater suitability for sustainable irrigation: A comprehensive study using indexical, statistical, and machine learning approaches. Groundwater for Sustainable Development, 24, 101059. doi:10.1016/j.gsd.2023.101059.

Ayotte, J. D., Montgomery, D. L., Flanagan, S. M., & Robinson, K. W. (2003). Arsenic in groundwater in eastern New England: Occurrence, controls, and human health implications. Environmental Science and Technology, 37(10), 2075–2083. doi:10.1021/es026211g.

Meyer, R., Engesgaard, P., & Sonnenborg, T. O. (2019). Origin and Dynamics of Saltwater Intrusion in a Regional Aquifer: Combining 3-D Saltwater Modeling with Geophysical and Geochemical Data. Water Resources Research, 55(3), 1792–1813. doi:10.1029/2018WR023624.

Nguyen, T. G., & Huynh, T. H. N. (2022). Assessment of surface water quality and monitoring in southern Vietnam using multicriteria statistical approaches. Sustainable Environment Research, 32(1), 20. doi:10.1186/s42834-022-00133-y.

Giao, N. T., Anh, P. K., & Nhien, H. T. H. (2021). Evaluating groundwater quality in Bac Lieu province using multivariate statistical method and groundwater quality index. Indonesian Journal of Environmental Management and Sustainability, 5(4), 129–135.

USGS. (2000). Classification of Natural Ponds and Lakes. United States Department of the Interior, Washington, United States.

Phuong, N. L., & Duong, M. T. (2018). Assessing the status of groundwater source in Thanh Khe district, Da Nang city. Journal of Science and Technology - University of Danang, 56-60. (In Vietnamese).

Hung, N. T. Q., Ky, N. M., Danh, D. H., Vu, T. P., & Tuan, H. N. A. (2018). Research on status of water use and quality of domestic supply water in Trang Bang district, Tay Ninh province. VNU Journal of Science: Earth and Environmental Sciences, 34(4), 10–21. doi:10.25073/2588-1094/vnuees.4251.

Anh, N. T., Ky, N. M., Hai, N. N., & Dung, B. Q. (2021). Assessment of the current status and risks caused by microorganisms in domestic water in peri-urban areas: A case study in Pleiku, Gia Lai province, Vietnam. Journal of Meteorology and Hydrology, 726, 12–24.

Trung, L. A. (2020). Evaluation of the change of permanganate index in domestic water stored in households. Journal of Science of Natural Resources and Environment, 30, 41–46. (In Vietnamese).

Nam, N. D. G., Akira, G., Kazutoshi, O., Trung, N. H., & Ngan, N. V. C. (2019). Assessment of Groundwater Quality and Its Suitability for Domestic and Irrigation Use in the Coastal Zone of the Mekong Delta, Vietnam. Advances in Global Change Research, 64, Springer, Cham, Switzerland. doi:10.1007/978-3-319-90400-9_10.

Cuong, L. P., & Thang, N. V. (2022). Application of machine learning model to predict groundwater quality: typical in Hoi An city, Quang Nam province. . Journal of Science and Technology - University of Danang, 20(5), 106–110.

Shu, J., Chen, M., Wu, H., Li, B., Wang, B., Li, B., Liu, R., & Liu, Z. (2019). An innovative method for synergistic stabilization/solidification of Mn2+, NH4+-N, PO43− and F− in electrolytic manganese residue and phosphogypsum. Journal of Hazardous Materials, 376, 212–222. doi:10.1016/j.jhazmat.2019.05.017.

Dung, B. X., Thanh, D. T. K., Quynh, K. T., & Phuc, D. T. T. (2020). Seasonal variation of groundwater level and quality in Xuan Mai, HaNoi, Vietnam. Journal of Forestry Science and Technology, 9, 80–90.

Shakya, B. M., Nakamura, T., Kamei, T., Shrestha, S. D., & Nishida, K. (2019). Seasonal groundwater quality status and nitrogen contamination in the shallow aquifer system of the Kathmandu Valley, Nepal. Water, 11(10), 2184. doi:10.3390/w11102184.

Wu, J., Zhang, Y., & Zhou, H. (2020). Groundwater chemistry and groundwater quality index incorporating health risk weighting in Dingbian County, Ordos basin of northwest China. Geochemistry, 80(4), 125607. doi:10.1016/j.chemer.2020.125607.

Majumdar, D., & Gupta, N. (2000). Nitrate pollution of groundwater and associated human health disorders. Indian journal of environmental health, 42(1), 28-39.

Podgorski, J., Araya, D., & Berg, M. (2022). Geogenic manganese and iron in groundwater of Southeast Asia and Bangladesh – Machine learning spatial prediction modeling and comparison with arsenic. Science of the Total Environment, 833, 155131. doi:10.1016/j.scitotenv.2022.155131.

Ullah, Z., Rashid, A., Ghani, J., Nawab, J., Zeng, X.-C., Shah, M., Alrefaei, A. F., Kamel, M., Aleya, L., Abdel-Daim, M. M., & Iqbal, J. (2022). Groundwater contamination through potentially harmful metals and its implications in groundwater management. Frontiers in Environmental Science, 10. doi:10.3389/fenvs.2022.1021596.

Sharma, G. K., Jena, R. K., Ray, P., Yadav, K. K., Moharana, P. C., Cabral-Pinto, M. M. S., & Bordoloi, G. (2021). Evaluating the geochemistry of groundwater contamination with iron and manganese and probabilistic human health risk assessment in endemic areas of the world’s largest River Island, India. Environmental Toxicology and Pharmacology, 87, 103690. doi:10.1016/j.etap.2021.103690.

Ha, N. T. T., Hang, H. T. T., Chi, D. P., Dung, D. T., & Huy, T. Q. (2019). Treatment of domestic wastewater and livestock wastewater by algae on the filter material. Vietnam Journal of Agricultural Science, 17(10), 826–834. (In Vietnamese).

Al-Hiyaly, S. A. K., Ali, Z. H., & Alobiady, A. A.-H. M. J. (2021). Removing of fat residues from domestic kitchen wastewater by synthetic filter of saw dust. IOP Conference Series: Earth and Environmental Science, 779(1), 012095. doi:10.1088/1755-1315/779/1/012095.

Nguyen, T., & Nguyen, L. (2018). Groundwater pollution by longstanding cemetery and solutions for urban cemetery planning in Ho Chi Minh City – from reality to solutions. MATEC Web of Conferences, 193, 02008. doi:10.1051/matecconf/201819302008.

Vaezihir, A., & Mohammadi, S. (2016). Groundwater contamination sourced from the main cemetery of Tabriz, Iran. Environmental Forensics, 17(2), 172–182. doi:10.1080/15275922.2016.1163621.

Jafarpoor Kandoli, S., Alidadi, H., Najafpoor, A. A., Mehrabpour, M., Hosseinzadeh, A., & Momeni, F. (2019). Assessment of cemetery effects on groundwater quality using GIS. Desalination and Water Treatment, 168, 235–242. doi:10.5004/dwt.2019.24622.

Costa, A. M., Alfaia, R. G. de S. M., & Campos, J. C. (2019). Landfill leachate treatment in Brazil – An overview. Journal of Environmental Management, 232, 110–116. doi:10.1016/j.jenvman.2018.11.006.

Stefania, G. A., Rotiroti, M., Buerge, I. J., Zanotti, C., Nava, V., Leoni, B., Fumagalli, L., & Bonomi, T. (2019). Identification of groundwater pollution sources in a landfill site using artificial sweeteners, multivariate analysis and transport modeling. Waste Management, 95, 116–128. doi:10.1016/j.wasman.2019.06.010.

Kumari, P., Gupta, N. C., Kaur, A., & Singh, K. (2019). Application of Principal Component Analysis and Correlation for Assessing Groundwater Contamination in and around Municipal Solid Waste Landfill of Ghazipur, Delhi. Journal of the Geological Society of India, 94(6), 595–604. doi:10.1007/s12594-019-1366-7.


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DOI: 10.28991/CEJ-2024-010-03-03

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